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An original solution of an inorganic sal...

An original solution of an inorganic salt in dilute `HCl` gives a brown colouration with potassium hexacyanidoferrate `(III)` and reddish brown colouration with sodium acetate solution. The cation of the salt is `:`

A

`Ni^(2+)`

B

`Fe^(3+)`

C

`Cu^(2+)`

D

none

Text Solution

Verified by Experts

The correct Answer is:
2

`Fe^(3+)+[Fe(CN)_(6)]^(3-)rarrFe[Fe(CN)_(5)]"brown colouration"`
`2Fe^(3+)+6CH_(3)COO^(-)+2H_(2)OhArr[Fe_(3)(OH)_(2)(CH_(3)COO)_(6)]^(+)+2H^(+)`
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