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Consider the following statements and pi...

Consider the following statements and pick out the wrong one.
`(1)` The solubility, thermal stability and th basic character of the hydroxides of alkaline earth metal increases from `Mg(OH)_(2)` to `Ba(OH)_(2)`.
`(2)` The dehydration of hydrated chlorides, bromides an iodides of `Ca, Sr` and `Ba` can be achieved on heating.
`(3)` The chlorides of both beryllium and aluminium are solubel in organic solvents and are strong Lewis acids.

A

`(1)` and `(2)` only

B

`(1)` and `(3)` only

C

`(1),(2)` and `(3)`

D

None

Text Solution

Verified by Experts

The correct Answer is:
4

`(1)` The solubility increases down the group because the change in lattice energy is more as compared to hydration energy. Thermal stability and the basic character both increases down the group as metallic character increases.
`(2)` It is correct statement.
`(3)` Beryllium and aluminium are diagonally related. Chlorides of both are covalent in nature and thus are soluble in organic solvents. Chlorides of both are electron deficient and thus act as strong Lewis acids.
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