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Phosphorus shows greater tendency for ca...

Phosphorus shows greater tendency for catenation than nitrogen. Why ?

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Due to smaller size, the Ione pairs of electrons on the two `N`-atoms repel the bond pair of `N-N` bond.In contrast, because of comparatively larger size of `P`, the Ione pairs of electrons on the two `P` atoms do not repel the bond pair of the `P-P` bond to the same extent.As a resultant, `N-N` single bond is weaker `(159 kJ mol^(-1))` than `P-P` single bond `(213 kJ mol^(-1))`.Consequently, nitrogen shows little tendency for catenation or phosphorus has greater tendency for catenation.
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How would you account for the following : (i) The electron gain enthalpy with negative sign is less for oxygen than that for sulphur. (ii) Phosphorus shows greater tandency for catenation than nitrogen. (iii) Fluorine never acts as the central atom in polyatomic interhalogen compounds.

(A) complete the following chemical equations : (i) Cu+HNO_(3) (dilute) to (ii) XeF_(4)+O_(2)F_(2)to (B) Explain the following observations: (i) Phosphorus has greater tendency for catentation than nitrogen. (ii) Oxygen is a gas but sulphur a solid. (iii) The halogens are coloured. Why ?

Draw the structures of the following : (i) XeF_(4) (ii) H_(2)S_(2)O_(7) (iii) Structure of SO_(3)^(2-) Exaplain the following observations : (b) Examplain the following observations : (i) Phosphours has a greater tendency for catenation than nitrogen. (ii) The negative value of electron gain enthalpy is less for fluorine than that for chlorine. (iii) Hydrogen fluoride has a much higher boiling point than hydrogen chloride.

Why does sulphur have greater tendency for catenation than oxygen ?

State reasons for each of the following : (i) All the P-Cl bonds in PCl_5 molecule are not equivalent. (ii) Sulphur has greater tendency for catenation than oxygen.

RESONANCE-P BLOCK ELEMENTS-B.L.E
  1. What is the basicity of H(3)PO(4) ?

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  2. Solid phosphorus pentachloride behaves as an ionic compound. Explain

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  3. Phosphorus shows greater tendency for catenation than nitrogen. Why ?

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  4. Give the chemical reaction to support that +5 oxidation state of Bi is...

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  5. Bi(V) and Sb(V) which may be a stronger oxidizing agent and why ?

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  6. Bi(2)O(3) is treated stronger oxidizing agent, write a balanced equati...

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  7. Sulphur disappears when boiled with an aqueous solution of sodium sulp...

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  8. Write one chemical reaction to show that conc. H(2)SO(4) can act as an...

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  9. Write the chemical equation for the following : Ca(3)(PO(4))(2) + Si...

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  10. Write balanced equation when NH(3) is dissolved in water.

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  11. What is the oxidation number of phosphorus in H(3)PO(2) molecule ?

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  12. Why is N(2) less reactive at room temperature ?

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  13. List the important sources of sulphur.

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  14. Why does O(3) act as a powerful oxidizing agent?

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  15. How is ozone estimated?

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  16. The HNH angle value is higher than HPH, HAsH and HSbH angles.Why ?

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  17. Nitrogen exists as diatomic molecule and phosphorus as P(4). Why ?

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  18. Among the hydrides of group 16, water shows unusual physical propertie...

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  19. Draw the structures of (i)PCl(5)(s), (ii)SO(3)^(2-)

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  20. On being slowly passed through water, PH(3) forms bubbles but NH(3) di...

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