Home
Class 12
CHEMISTRY
Give the chemical reaction to support th...

Give the chemical reaction to support that `+5` oxidation state of `Bi` is less stable than `+3` state.

Text Solution

Verified by Experts

Due to inert pair effect, `Bi` can show `+3` and `+5` oxidation states. Since the inert pair effect is maximum in case of `Bi`, therefore, its `+5` oxidation state is less stable than `+3` oxidation state.This is evident from the observation that `BiCl_(3)` even on prolonged heating with `Cl_(2)` does not form `BiCl_(5)`
Promotional Banner

Topper's Solved these Questions

  • P BLOCK ELEMENTS

    RESONANCE|Exercise Exercise 1 part-1|14 Videos
  • P BLOCK ELEMENTS

    RESONANCE|Exercise Exercise 1 part-2|32 Videos
  • P BLOCK ELEMENTS

    RESONANCE|Exercise ALP PART OBJECTIVE|12 Videos
  • NUCLEAR CHEMISTRY

    RESONANCE|Exercise STAGE-II|1 Videos
  • P-BLOCK ELEMENT (BORON AND CARBON FAMILY)

    RESONANCE|Exercise PART - III : OLYMPIAD PROBLEMS (PREVIOUS YEARS) STAGE - V (INTERNATIONAL CHEMISTRY OLYMPIAD (IChO)) Problem 3|8 Videos

Similar Questions

Explore conceptually related problems

The oxidation state of -3 is least stable in

Most stable oxidation state of iron is

Most stable oxidation state of gold is:

RESONANCE-P BLOCK ELEMENTS-B.L.E
  1. Solid phosphorus pentachloride behaves as an ionic compound. Explain

    Text Solution

    |

  2. Phosphorus shows greater tendency for catenation than nitrogen. Why ?

    Text Solution

    |

  3. Give the chemical reaction to support that +5 oxidation state of Bi is...

    Text Solution

    |

  4. Bi(V) and Sb(V) which may be a stronger oxidizing agent and why ?

    Text Solution

    |

  5. Bi(2)O(3) is treated stronger oxidizing agent, write a balanced equati...

    Text Solution

    |

  6. Sulphur disappears when boiled with an aqueous solution of sodium sulp...

    Text Solution

    |

  7. Write one chemical reaction to show that conc. H(2)SO(4) can act as an...

    Text Solution

    |

  8. Write the chemical equation for the following : Ca(3)(PO(4))(2) + Si...

    Text Solution

    |

  9. Write balanced equation when NH(3) is dissolved in water.

    Text Solution

    |

  10. What is the oxidation number of phosphorus in H(3)PO(2) molecule ?

    Text Solution

    |

  11. Why is N(2) less reactive at room temperature ?

    Text Solution

    |

  12. List the important sources of sulphur.

    Text Solution

    |

  13. Why does O(3) act as a powerful oxidizing agent?

    Text Solution

    |

  14. How is ozone estimated?

    Text Solution

    |

  15. The HNH angle value is higher than HPH, HAsH and HSbH angles.Why ?

    Text Solution

    |

  16. Nitrogen exists as diatomic molecule and phosphorus as P(4). Why ?

    Text Solution

    |

  17. Among the hydrides of group 16, water shows unusual physical propertie...

    Text Solution

    |

  18. Draw the structures of (i)PCl(5)(s), (ii)SO(3)^(2-)

    Text Solution

    |

  19. On being slowly passed through water, PH(3) forms bubbles but NH(3) di...

    Text Solution

    |

  20. Mention the conditions required to maximise the yield of ammonia.

    Text Solution

    |