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{:(Column-I," "Column-II),(PCI(5...

`{:(Column-I," "Column-II),(PCI_(5)overset("moist")underset("Air")to," "(p)"Hydrolysis"),(P_(4)+NaOH("conc.")+H_(2)Ooverset("Warm")to," ""(q)At least one of the products has tetrahedral hybridisation"),(H_(3)PO_(3)overset(Delta)to," "(r)"Disproporationation"),(P_(4)O_(6)+H_(2)O overset(Delta)to," "(s)"At least one of the products has" `ppi`-`dpi` "bonding"):}`

Text Solution

Verified by Experts

(A) `PCI_(5)+H_(2)Ooverset("Hydrolysis")tounderset(sp^(3))(POCI)+2HCI`
`POCI+3H_(2)Oto underset(sp^(3))(H_(3)PO_(4))+3HCI`,
(B) `P_(4)+3NaOH+3H_(2)Ooverset(Delta)underset(co_(2))to3PH_(3)+3NaH_(2)PO_(2) or H_(2)PO_(2)^(-) ,
(C) "Disproportionation reaction".
`4H_(3)PO_(3)overset(Delta)to 3H_(3)PO_(4)+PH_(3)`(Alkaline hydrrolysis)
(D) `P_(4)O_(6)+6H_(2)O(Hot)overset(Delta)underset(Hydrolysis)to3H_(3)PO_(4)+PH_(3)`
`P_(4)O_(6)+6H_(2)Oto4H_(2)PO_(3)`
(e)`4H_(3)PO_(3)overset(Delta)to3H_(3)PO_(4)+PH`
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