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Statement -1 : Sodium thiosulphate is no...

Statement -1 : Sodium thiosulphate is not prepared by boiling `Na_(2)SO_(3)` with S in acidic medium.
Statement -2 : `Na_(2)S_(2)O_(3)+H^(+) to 2Na++H_(2)SO_(3)+Sdarr`

A

Statement -1 is true , Statement-2 is true, Statement-2 is a correct explantion for Statement -1.

B

Statement -1 and Statement- 2 both are False.

C

Statement -1 is true, Statement- 2 is false.

D

Statement -1 is true, Statement- 2 is false.

Text Solution

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The correct Answer is:
A
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Na_(2)S_(2)O_(3) is prepared by :

Na_(2)S_(3)+2Ooverset(Delta)to Na_(2)SO_(4)+2S .

Na_(2)S_(2)O_(3) can be prepared by:

Na_(2)O_(2) + H_(2)SO_(4) to

AgI darr+2Na_(2)S_(2)O_(3) to Na_(3)[Ag(S_(2)O_(3))_(2)]+NaI

Na_(2)S+H_(2)SO_(4)("Conc.")to S darr+SO_(2)+Na_(2)SO_(4)

Select the correct statements about Na_(2)S_(2)O_(3).5H_(2)O :

S_(8)+NaOH to Na_(2)S+Na_(2)S_(2)O_(3)