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Predict the formulae of the stable bin...

Predict the formulae of the stable binary compounds that would be formed by the following pairs of elements (a) silicon and oxygen (b) aluminium and bromine ( c ) calcium and iodine (d) element 114 and fluorine (e ) element 120 and oxygen.

Text Solution

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(a) Silicon belongs to group 14. it has four valence electrons and hence its valence= 4 Oxygen belong to group 16. It has six electrons in the valence shell and hence its valence =8-6 =2 . Therefore the formula of silicon oxide= `SiO_(2)`.
( b) Aluminium belongs to group 13. It has three electron in the valence shell and hence its valence =3.
Bromine belongs to group 17. It has seven electrons in the valence shell and hence its valence =8-7 =1
Therefore formula of aluminium bromide= `AIBr_(3)`
(c ) Calcium belongs to group 2. It has two -electrons in the valence shell and hence its valence =2 .Iodine belongs to group 17. It has seven valence electrons and hence its valence =8-7=1.
Therefore formula of calcium iodic= `Cal_(2)`
(d )In the 7th period the 4th transition series ends at element with Z =112, therefore filing of 7p- subshell will begin with element Z=113 .Hence element with Z= 114 will have two electrons in 7p- orbitals and two electrons in 7 s-orbital .In other words the element Z= 114 will lie in group 14 and hence its valence =4
fluorine belongs to group 17 with seven valence electrons and hence its valence =8-7=1
Therefore formula of compound formed by element 114 and fluorine is `MF_(4)` where M represents the element
(e) The 7th period ends at element with Z= 118. Therefore filling of 8th shell i.e., 8 s-orbital will begin with element Z= 119 and consequently with Z= 120 will belong to group 2 and its valence will be =2
Oxygen belongs to group 16 with six valence electrons and hence its valence =8-6=2.
Therefore formula of compound formed by element Z= 120 and oxygen will be MO where M respresent element.
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