Home
Class 11
CHEMISTRY
In each of the following questions a...

In each of the following questions a Statement of Assertion (A ) is given followed by a corresponding statement of Reason (R ) Just below it . Of the statement mark the correct answer as
Assertion. First ionization energy for nitrogen is lower than that of oxygen .
Reason . Across a period effective nuclear charge decreases.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given Assertion (A) and Reason (R), we need to break down the statements and evaluate their correctness. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "First ionization energy for nitrogen is lower than that of oxygen." - Ionization energy is the energy required to remove an electron from an atom in its gaseous state. 2. **Evaluating the Ionization Energies**: - The electronic configuration of nitrogen (N) is 1s² 2s² 2p³, while that of oxygen (O) is 1s² 2s² 2p⁴. - Generally, ionization energy increases across a period due to increasing nuclear charge, which holds the electrons more tightly. - However, between nitrogen and oxygen, the ionization energy of nitrogen is actually higher than that of oxygen due to the stability of the half-filled p subshell in nitrogen. 3. **Understanding the Reason**: - The reason states that "Across a period effective nuclear charge decreases." - This statement is incorrect. Effective nuclear charge actually increases across a period because as protons are added to the nucleus, the positive charge increases, pulling the electrons closer and making them harder to remove. 4. **Conclusion**: - Since the assertion is false (first ionization energy of nitrogen is higher than that of oxygen) and the reason is also false (effective nuclear charge increases across a period), both statements are incorrect. ### Final Answer: - Both Assertion (A) and Reason (R) are false.

To analyze the given Assertion (A) and Reason (R), we need to break down the statements and evaluate their correctness. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that "First ionization energy for nitrogen is lower than that of oxygen." - Ionization energy is the energy required to remove an electron from an atom in its gaseous state. ...
Promotional Banner

Topper's Solved these Questions

  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    PRADEEP|Exercise Competition Focus (Jee Main and Advanced / Medical Entrance ) ( Assertion - Reason Type Question ) (Type I)|6 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    PRADEEP|Exercise Curiosity Questions|2 Videos
  • ENVIRONMENTAL CHEMISTRY

    PRADEEP|Exercise COMPETITION FOCUS (JEE(Main and Advanced)/Medical Entrance (VI.ASSERTION-REASON) Type II|6 Videos