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Chlorine is used to purify drinking wate...

Chlorine is used to purify drinking water. Excess of chlorine is harmful. The excess of chlorine is removed by treating with sulphur dioxide. Present a balanced equation for this redox change taking place in water.

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The skeletal equation is `CI_(2)(aq)+SO_(2)+H_(2)(l)rarrCI^(-)(aq)+SO_(4)^(2-)(aq)`
Reduction half equation `CI_(2)(aq)rarrCI^(-)(aq)`
oxidation half equation `overset(+4)SO_(2)(aq)rarroverset(+6)SO_(4)^(2-)(aq)`
oxidation addding Eq (i) and Eq (ii) we have
`SO_(2)(aq)+2H_(2)O(l)rarrSO_(4)^(2-)(aq)+4H^(+)(aq)+2e^(=)`
adding Eq (i) and Eq (ii) we have
`CI_(2)(aq)+SO_(23)+2H_(2)O(l)rarr2CI^(-)(aq)+SO_(4)^(2-)(aq)+4H^(+)(aq)`
this represents the balance redox reaction
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