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The standard reduction potential data at...

The standard reduction potential data at `25^(@)C` is given below
`E^(@) (Fe^(3+), Fe^(2+)) = +0.77V`,
`E^(@) (Fe^(2+), Fe) = -0.44V`,
`E^(@) (Cu^(2+),Cu) = +0.34V`,
`E^(@)(Cu^(+),Cu) = +0.52 V`,
`E^(@) (O_(2)(g) +4H^(+) +4e^(-) rarr 2H_(2)O] = +1.23V`
`E^(@) [(O_(2)(g) +2H_(2)O +4e^(-) rarr 4OH^(-))] = +0.40V`,
`E^(@) (Cr^(3+), Cr) =- 0.74V`,
`E^(@) (Cr^(2+),Cr) = - 0.91V`,
Match `E^(@)` of the redox pair in List-I with the values given in List-II and select the correct answer using the code given below teh lists:
`{:(List-I,List-II),((P)E^(@)(Fe^(3+),Fe),(1)-0.18V),((Q)E^(@)(4H_(2)O hArr 4H^(+)+4OH^(+)),(2)-0.4V),((R)E^(@)(Cu^(2+)+Curarr2Cu^(+)),(3)-0.04V),((S)E^(@)(Cr^(3+),Cr^(2+)),(4)-0.83V):}`
Codes:

A

`{:(P,Q,R,S),(4,1,2,3):}`

B

`{:(P,Q,R,S),(1,2,3,4):}`

C

`{:(P,Q,R,S),(2,3,4,1):}`

D

`{:(P,Q,R,S),(3,4,1,2):}`

Text Solution

Verified by Experts

The correct Answer is:
d
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