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The following compounds have been arrang...

The following compounds have been arranged in the order of their increasing thermal stabilities. Identify the correct order.
`K_(2)CO_(3)(I),Na_(2)CO_(3)(II),Rb_(2)CO_(3)(III),Li_(2)CO_(3)(IV)`

A

`I lt II lt III lt IV`

B

`IV lt II lt III lt I`

C

`IV lt II lt I lt III`

D

`II lt IV lt III lt I`

Text Solution

Verified by Experts

The correct Answer is:
3

The thermal stabilites of carbonates increase down the group due to increase in metallic character `i.e.` electropositive character . Further bigger cation stabiliese bigger anion through crystal lattice energy effects.
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