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Barium ion , CN^(-) and Co^(2+) form an ...

Barium ion , `CN^(-)` and `Co^(2+)` form an ionic complex . If that complex is supposed to be `75%` ionised in water with van't Hoff factor `'i'` equal to four , then the coordination number of `Co^(2+)` in the complex can be :

A

6

B

4

C

`6 & 4` both possible

D

5

Text Solution

Verified by Experts

The correct Answer is:
4

`alpha=(i-1)/(x xx1)=(3)/(4)=(4-1)/(x-1)" ":.x=5" ":." "` Complex is `Ba_(3)[Co(CN)_(5)]_(2)`
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