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Depression in f.p. of an aqueous urea so...

Depression in `f.p.` of an aqueous urea solutio is `1.86^(@) .(K_(f)=1.86^(@) mol^(-1) kg)` Hence, mole`-` fraction of urea in this soluiton is `:

A

`0.982`

B

`0.567`

C

`0.943`

D

`0.018`

Text Solution

Verified by Experts

The correct Answer is:
4

As `DeltaT_(f)=` molality `xxK_(f)`
`1.86=mxx1.86`
molality `=1 mol kg^(-1)`
`:. " "` urea `=1 mol`
moles of water `=(1000)/(18)=55.55`
mole fraction of urea `=(1)/(55.55)=0.018`
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