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A racemic mixture of 2- Chloropropanoic ...

A racemic mixture of `2-` Chloropropanoic acid is treated with excess of `(+)-2-` Butanol. The reaction can be represented as follows `:`
`CH_(2)-underset((pm))underset(Cl)underset(|)(CH)-COOH+CH_(3)-underset(" "(+)" excess")underset(OH)underset(|)(CH)-CH_(2)-CH_(3) rarr CH_(3)-underset(Cl)underset(|)(CH)-COO-overset(" "CH_(3))overset(|)(CH)-CH_(2)-CH_(3)+CH_(3)-underset((+)" (Left unreacted)")underset(OH)underset(|)(CH)-CH_(2)-CH_(3)`

A

only one optically pure ester is obtained

B

A mixture of two ester ( enantiomers ) is obtained

C

A mixture of four stereoisomers of ester is obtained

D

All esters formed are optically active

Text Solution

Verified by Experts

The correct Answer is:
4

Esters formed have two different chiral central, so they are optically active.
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The IUPAC name for CH_(3) - underset(OH)underset(|)(CH) - CH_(2) - underset(OH)underset(|)overset(CH_(3))overset(|)(C) - CH_(3) is:

CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)-underset(O)underset(||)(C)-NHCH_(3)

Write IUPAC name of CH_(3)-underset(Cl)underset(|)(CH)-underset(COOH)underset("| ")(CH)-CH_(3)

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