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The correct increasing order of the reac...

The correct increasing order of the reactivity of halides for `S_(N)` 1 reaction is `:`

A

`{:(CH_(3)-CH_(2)-X,lt,(CH_(3))_(2)CH-X,lt,CH_(2)=CH-CH_(2)-X,lt,PhCH_(2)-X),(,,,,,,):}`

B

`{:((CH_(3))_(2)CH-X,lt,CH_(3)-CH_(2)-X,lt,CH_(2),lt,PhCH_(2)-X),(,,,,,,):}`

C

`{:(PhCH_(2)-X,lt,(CH_(3))_(2)CH-X,lt,CH_(2)-CH_(2)-X,lt,CH_(2)=CH-CH_(2)-X),(,,,,,,):}`

D

`{:(CH_(2)=CH-CH_(2)-X,lt,Ph-CH_(2)-X,lt,(CH_(3))_(2)CH-X,lt,CH_(3)-CH_(2)-X),(,,,,,,):}`

Text Solution

Verified by Experts

The correct Answer is:
1

The relative stability of alkyl carbocation is due to inductive effect hyperconjugation, while that of stable carbocation is due to resonance. The order is `:`
`CH_(3)CH_(2)X lt (CH_(3))_(2)CH-X lt CH_(2)=CH-CH_(2)X lt PhCH_(2)-X`
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