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PhNO(2) underset(NH(4)Cl)overset(Zn)to A...

`PhNO_(2) underset(NH_(4)Cl)overset(Zn)to A underset("Tollen's Reagent")overset(AgNO_(3), NH_(4)OH)toB` (organic compound). Which is/are incorrect?

A

A gives Tollen's test

B

A shows tautomerism

C

A is aniline

D

A foms complex with Tollen's reagent but not gives silver mirror

Text Solution

Verified by Experts

The correct Answer is:
B, C, D

`A` is `PhNHOH, B` is `PhNO`
`PhNHOH overset(T.R) (to) Ag+PhNO`
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X(C_(4)H_(9)Br) underset(Delta) overset(alc.KOH)to Yoverset(Br_(2)//"CC"l_(4)) rarrZ underset(Delta) overset(NaNH_(2)(2eq.))to W underset(("Tollen's reagent")) overset(AgNO_(3)+NH_(4)OH)to white ppt Which of the following statement(s) is//are incorrect?

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PhCH_(3)underset(hv)overset(Cl_(2))to(A)underset("ether")overset(Mg)to(B)underset(NH_(4)Cl)overset(CH_(3)CHO)to(C)

Tollen's reagment (AgNO_(3)+NH_(4)OH) can be used to distinguish between :

X overset(NH_(3)//Delta)toB underset(Delta)overset(KOBr)to overset(HNO_(2))to(CH_(3))_(3)C-OH,X is :

CrCl_(3) underset(NH_(4)OH)overset(NH_(4)Cl)to (A) underset(H_(2)O)overset(Na_(2)O_(2))to (B) underset("acetate")overset("Lead")to(C) In this reaction sequence, the compound (C) is:

Cl-underset(Cl)underset(|)overset(Cl)overset(|)(C)-underset(H)underset(|)overset(OH)overset(|)(C)-OH

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