Home
Class 12
CHEMISTRY
How many of the following species are pa...

How many of the following species are paramagnetic?
`N_(2)^(+), O_(2)^(-), B_(2), C_(2), CN^(-), NO^(+), CO, H_(2)^(-), He_(2)^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine how many of the given species are paramagnetic, we need to analyze the number of valence electrons in each species and check if they have unpaired electrons. A species is considered paramagnetic if it has one or more unpaired electrons. ### Step-by-Step Solution: 1. **N₂⁺ (Nitrogen Dimer Cation)** - Nitrogen (N) has 5 valence electrons. - For N₂, there are 10 valence electrons (5 from each nitrogen). - N₂⁺ has one less electron: 10 - 1 = 9 electrons. - The electron configuration shows that there will be unpaired electrons. - **Conclusion**: N₂⁺ is paramagnetic. 2. **O₂⁻ (Oxygen Dimer Anion)** - Oxygen (O) has 6 valence electrons. - For O₂, there are 12 valence electrons (6 from each oxygen). - O₂⁻ has one extra electron: 12 + 1 = 13 electrons. - The electron configuration shows that there will be unpaired electrons. - **Conclusion**: O₂⁻ is paramagnetic. 3. **B₂ (Boron Dimer)** - Boron (B) has 3 valence electrons. - For B₂, there are 6 valence electrons (3 from each boron). - The electron configuration shows that all electrons are paired. - **Conclusion**: B₂ is not paramagnetic. 4. **C₂ (Carbon Dimer)** - Carbon (C) has 4 valence electrons. - For C₂, there are 8 valence electrons (4 from each carbon). - The electron configuration shows that all electrons are paired. - **Conclusion**: C₂ is not paramagnetic. 5. **CN⁻ (Cyanide Anion)** - Carbon has 4 valence electrons and nitrogen has 5. - Total for CN: 4 + 5 = 9 valence electrons. - CN⁻ has one extra electron: 9 + 1 = 10 electrons. - The electron configuration shows that all electrons are paired. - **Conclusion**: CN⁻ is not paramagnetic. 6. **NO⁺ (Nitric Oxide Cation)** - Nitrogen has 5 valence electrons and oxygen has 6. - Total for NO: 5 + 6 = 11 valence electrons. - NO⁺ has one less electron: 11 - 1 = 10 electrons. - The electron configuration shows that there will be unpaired electrons. - **Conclusion**: NO⁺ is paramagnetic. 7. **CO (Carbon Monoxide)** - Carbon has 4 valence electrons and oxygen has 6. - Total for CO: 4 + 6 = 10 valence electrons. - The electron configuration shows that all electrons are paired. - **Conclusion**: CO is not paramagnetic. 8. **H₂⁻ (Hydrogen Dimer Anion)** - Each hydrogen has 1 valence electron. - For H₂, there are 2 valence electrons. - H₂⁻ has one extra electron: 2 + 1 = 3 electrons. - The electron configuration shows that there will be unpaired electrons. - **Conclusion**: H₂⁻ is paramagnetic. 9. **He₂⁺ (Helium Dimer Cation)** - Each helium has 2 valence electrons. - For He₂, there are 4 valence electrons. - He₂⁺ has one less electron: 4 - 1 = 3 electrons. - The electron configuration shows that there will be unpaired electrons. - **Conclusion**: He₂⁺ is paramagnetic. ### Summary of Results: - Paramagnetic species: N₂⁺, O₂⁻, NO⁺, H₂⁻, He₂⁺ - Total paramagnetic species = 5 ### Final Answer: **5 species are paramagnetic.**

To determine how many of the given species are paramagnetic, we need to analyze the number of valence electrons in each species and check if they have unpaired electrons. A species is considered paramagnetic if it has one or more unpaired electrons. ### Step-by-Step Solution: 1. **N₂⁺ (Nitrogen Dimer Cation)** - Nitrogen (N) has 5 valence electrons. - For N₂, there are 10 valence electrons (5 from each nitrogen). - N₂⁺ has one less electron: 10 - 1 = 9 electrons. ...
Promotional Banner

Topper's Solved these Questions

  • STOICHIOMETRY AND BALANCING REDOX REACTION

    FIITJEE|Exercise SINGLE INTEGER ANSWER TYPE QUESTIONS|5 Videos
  • THERMODYNAMICS AND THERMOCHEMISTRY

    FIITJEE|Exercise SINGLE INTEGER ANSWER TYPE QUESTIONS|5 Videos

Similar Questions

Explore conceptually related problems

How many of the following are paramagnetic? MgO,KO_2,Na_2O_2,BaO_2,BeO,CaO,Li_2O

How many of the following are neutral CO, NO, N_(2)O, CO_(2),NO_(2), ZnO, CaO, H_(2)O

Compare the relative stabilities and magnetic behaviour of the following species (a) O_(2)^(Θ) and N_(2)^(o+) (b) O_(2)^(2-) and N_(2)^(Θ) (c ) O_(2)^(2-) and N_(2)^(2-) .

How many of the following species have bond order of 2.5 ? N_(2)^(o+) (ii) N_(2)^(Theta) (iii) O_(2)^(o+) (iv) O_(2)^(Theta) (v) NO (vi) CN .

Total number of species which has/ have symmetrical electronic distribution in their HOMO and also paramagnetic. N_(2)^(+), O_(2)^(2-), C_(2), O_(2), B_(2), C_(2)^(2-), N_(2)^(2-) .

FIITJEE-TEST PAPERS-CHEMISTRY
  1. 4 mol of a mixture containing one mol each of LiNO(3), NaNO(3), Ca(NO(...

    Text Solution

    |

  2. The velocity of an electron in the orbit of hydrogen atom is 5.47xx10^...

    Text Solution

    |

  3. How many of the following species are paramagnetic? N(2)^(+), O(2)^(...

    Text Solution

    |

  4. 6ml of 0.1M CH(3)COOH when mixed with x ml of 0.1 M NaOH the pH of the...

    Text Solution

    |

  5. For the reaction A(g)hArrB(g)+C(g) At 300K, the average molecular ...

    Text Solution

    |

  6. 10 ml of M/10 NH(4)OH is mixed with4ml of M/10H(2)SO(4) solution. The ...

    Text Solution

    |

  7. A catalyst lower the activation energy of a reaction from 200KJ "mol"^...

    Text Solution

    |

  8. Which of the following reation is incorrect?

    Text Solution

    |

  9. Which of the following statement is/are correct?

    Text Solution

    |

  10. The incorrect statement(s) among the following is/are?

    Text Solution

    |

  11. Which of the following is/are pyroscilicate?

    Text Solution

    |

  12. Which of the following statement(s) is/are correct?

    Text Solution

    |

  13. Which of the following statement(s) is/are correct for the following e...

    Text Solution

    |

  14. Solid AgNO(3) is gradually added to a solution which is 0.01M n Cl^(-)...

    Text Solution

    |

  15. Solid AgNO(3) is gradually added to a solution which is 0.01M n Cl^(-)...

    Text Solution

    |

  16. In a hydrogen atom the de-Broglie wavelength of an electron is 1.67nm....

    Text Solution

    |

  17. For the redox reaction xCr(OH)(3)+YlO(3)^(-)+zOH^(-)toxCrO(4)^(2-)+y...

    Text Solution

    |

  18. The following equilibrium exists in a closed vessel in 1L capacity A(g...

    Text Solution

    |

  19. A vessel at 1000K contains CO(2)(g) at 2 atm pressure. When graphite i...

    Text Solution

    |

  20. The half -lie period for the decomposition of AB(2)(g) at 100mm pressu...

    Text Solution

    |