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The suitable reagent to convert CH(3)-CH...

The suitable reagent to convert `CH_(3)-CH=CH-CHO` into `CH_(3)-CH_(2)-CH_(2)-CH_(2)-OH`

A

`NaBH_(4)`

B

`LiAIH_(4)`

C

`Zn-Hg//HCI`

D

`H_(2)//Pd`

Text Solution

AI Generated Solution

The correct Answer is:
To convert the compound `CH₃-CH=CH-CHO` (which is an allylic aldehyde) into `CH₃-CH₂-CH₂-CH₂OH` (a primary alcohol), we need to perform a reduction that targets both the double bond and the aldehyde functional group. Here’s how we can approach this step by step: ### Step 1: Identify the Functional Groups The starting compound `CH₃-CH=CH-CHO` contains: - An aldehyde group (-CHO) - A carbon-carbon double bond (C=C) The target compound `CH₃-CH₂-CH₂-CH₂OH` is a primary alcohol, which means we need to reduce both the aldehyde and the double bond. ### Step 2: Choose the Suitable Reagent To achieve the desired transformation, we need a reagent that can reduce both the double bond and the aldehyde. 1. **NaBH₄ (Sodium Borohydride)**: This reagent is selective for aldehydes and ketones but does not reduce alkenes (double bonds). So, it is not suitable. 2. **LiAlH₄ (Lithium Aluminium Hydride)**: This is a strong reducing agent that can reduce aldehydes and ketones to alcohols, but it does not reduce double bonds. Therefore, it is also not suitable. 3. **Zn/HCl (Clemenson Reduction)**: This method is used to reduce aldehydes to alkanes but does not affect double bonds. Hence, it is not suitable for our purpose. 4. **H₂/Pd (Hydrogenation)**: This reagent can reduce both alkenes and aldehydes. Under the right conditions, it can convert the double bond to a single bond and the aldehyde to an alcohol. This makes it the most suitable reagent for our reaction. ### Step 3: Perform the Reaction Using H₂ in the presence of a palladium catalyst (Pd), we can perform the following transformations: - The double bond (C=C) will be hydrogenated to a single bond (C-C). - The aldehyde group (-CHO) will be reduced to a primary alcohol (-CH₂OH). ### Final Answer Thus, the suitable reagent to convert `CH₃-CH=CH-CHO` into `CH₃-CH₂-CH₂-CH₂OH` is **H₂/Pd**. ---

To convert the compound `CH₃-CH=CH-CHO` (which is an allylic aldehyde) into `CH₃-CH₂-CH₂-CH₂OH` (a primary alcohol), we need to perform a reduction that targets both the double bond and the aldehyde functional group. Here’s how we can approach this step by step: ### Step 1: Identify the Functional Groups The starting compound `CH₃-CH=CH-CHO` contains: - An aldehyde group (-CHO) - A carbon-carbon double bond (C=C) The target compound `CH₃-CH₂-CH₂-CH₂OH` is a primary alcohol, which means we need to reduce both the aldehyde and the double bond. ...
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