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(a) In the following equilibrium N(2)O(4...

(a) In the following equilibrium `N_(2)O_(4)(g)hArr2NO_(2)(g)` when 5 moles of each are taken, the temperature is kept at `298K` the total pressure was found to be 20 bar. Given that `DeltaG_(f)^(@)(N_(2)O_(4))=100kJ, DeltaG_(f)^(@)(NO_(2))=50kJ`
(i) Find `DeltaG` of the reaction.
(ii) The direction of th reaction in which the equilibrium shifts.
(b) A graph is plotted for a real gas which follows van der Waals' equation with `pV_(m)` taken on `Y`-axis and `p` on `X`-axis.
Find the intercept of the ine where `V_(m)` is molar volume.

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In the reaction equilibrium N_(2)O_(4) hArr 2NO_(2)(g) When 5 mol of each is taken and the temperature is kept at 298 K , the total pressure was found to be 20 bar. Given : Delta_(f)G_(n_(2)O_(4))^(ɵ)=100 kJ, Delta_(f)G_(NO_(2))^(ɵ)=50 KJ a. Find DeltaG of the reaction at 298 K . b. Find the direction of the reaction.

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