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A tertiary alcohol (H) upon acid-catalys...

A tertiary alcohol (H) upon acid-catalysed dehydration gives a product (I). Ozonolysis of (I) leads to compounds (J) and (K). Compound (J) upon reaction with KOH gives benzyl alcohol and a compound (L), whereas (K) on reaction with KOH gives only (M).

The structures of compounds (J), (K), and (L), respectively, are:

A

`PhCOCH_(3),PhCH_(2)COCH_(3)` and `PhCH_(2)CO O^(-)K^(+)`

B

`PhCHO,PhCH_(2)CHO` and `PhCOO^(-)K^(+)`

C

`PhCOCH_(3),PhCH_(2)CHO` and `CH_(3)CO O^(-)K^(+)`

D

`PhCHO,PhCOCH_(3)` and `PhCOO^(-)K^(+)`

Text Solution

Verified by Experts

The correct Answer is:
D
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A tertiary alcohol (H) upon acid-catalysed dehydration gives a product (I). Ozonolysis of (I) leads to compounds (J) and (K). Compound (J) upon reaction with KOH gives benzyl alcohol and a compound (L), whereas (K) on reaction with KOH gives only (M). The structurer of compound (I) is:

A tertiary alcohol (H) upon acid-catalysed dehydration gives a product (I). Ozonolysis of (I) leads to compounds (J) and (K). Compound (J) upon reaction with KOH gives benzyl alcohol and a compound (L), whereas (K) on reaction with KOH gives only (M). Compound (H) is formed by the reaction of:

The compound (J) and (K), respectively, are: