`PCl_(3)` on hydrolysis gives

Statement -1 : Hydrolysis of NCl_(3) gives NH_(4)OH and HOCl while PCl_(3) on hydrolysis gives H_(3)PO_(3) and HCl. Statement -2 : The difference is due to the change in polarity of P^(+sigma)-CI^(-sigma) bond in PCl_(3) in contrast to N^(-sigma)-CI^(+sigma) bond in NCl_(3) .

PCl_(5) on hydrolysis gives

Statement -1 : Hydrogen of NCl_(3) gives NH_(4)OH and HOCl while PCl_(3) on hydrolysis gives H_(3)PO_(3) and HCl. Statement -2 : The difference is due to the change in polarity of P^(+sigma)-CI^(-sigma) bond in PCI_(3) in contrast to N^(-sigma)-CI^(+sigma) bond in NCI_(3) .

AlCl_(3) on hydrolysis gives

PCI_(3) on hydrolysis gives

AlCl_(3) on hydrolysis gives

PCl_(3) on hydrolysis give fumes of -