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Calculate total entropy change for the t...

Calculate total entropy change for the transition of 1 mole of solid sulphur from its monoclinic form to the rhombic form at 400 K, id `DeltaH=-400J//"mole"` for this transition and assume the surrounding to be in a bath of water at `27^(@)C`

A

`-1J//k`

B

`+0.33J//k`

C

`1.67J//k`

D

`0.66J//k`

Text Solution

Verified by Experts

The correct Answer is:
B

`DeltaS_(sys)=-(400)/(400)=-1J//k`
`DeltaS_("surr")=+(400)/(300)=(4)/(3)J//k`
`DeltaS_(T)=-1+(4)/(3)=+(1)/(3)J//k`
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