`(C_(6)H_(12))overset(HCl)rarr underset((C_(6)H_(13)Cl))(B)+(C )` `(B)overset(Alc.KOH)rarr(D)` [isomer of (A)] `(D)overset("Ozonolysis")rarr(E )` (It gives negative test with Fehling's solution but responds to iodoform test) `(A)overset("Ozonolysis)rarr(F)+(G)` (Both give positive Tollens test but do not give iodoform test) `(F)+(G)overset("Conc.NaOH)rarr HCOONa` + A primary alcohol . Identify A to G.
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From the following sequence of reactions , [A] (C_(6)H_(12)) overset(HCl)(rarr) (B) (C_(6) H_(13)Cl) + (C) (C_(6)H_(13)Cl) react with AgNO_(3) to give white ppt. [B] overset("Alc." KOH)(to) (D) (An isomer of A ) gives positive test with Br_(2)//C Cl_(4) [D] overset("Ozonelysis")(to) (E) gives positive iodoform test and negative Fehling's test . [A] overset("Ozonolysis")(to) (F) + (G) , both F and G give positive Tollen's test . [F] + [G] underset(Delta)overset("Conc." NaOH)(to) HCOONa + alcohol The reaction involve in F and G with the NaOH is : The structure of compound D is :
From the following sequence of reactions , [A] (C_(6)H_(12)) overset(HCl)(rarr) (B) (C_(6) H_(13)Cl) + (C) (C_(6)H_(13)Cl) react with AgNO_(3) to give white ppt. [B] overset("Alc." KOH)(to) (D) (An isomer of A ) gives positive test with Br_(2)//C Cl_(4) [D] overset("Ozonelysis")(to) (E) gives positive iodoform test and negative Fehling's test . [A] overset("Ozonolysis")(to) (F) + (G) , both F and G give positive Tollen's test . [F] + [G] underset(Delta)overset("Conc." NaOH)(to) HCOONa + alcohol The structure A and B respectively are :
From the following sequence of reactions , [A] (C_(6)H_(12)) overset(HCl)(rarr) (B) (C_(6) H_(13)Cl) + (C) (C_(6)H_(13)Cl) react with AgNO_(3) to give white ppt. [B] overset("Alc." KOH)(to) (D) (An isomer of A ) gives positive test with Br_(2)//C Cl_(4) [D] overset("Ozonelysis")(to) (E) gives positive iodoform test and negative Fehling's test . [A] overset("Ozonolysis")(to) (F) + (G) , both F and G give positive Tollen's test . [F] + [G] underset(Delta)overset("Conc." NaOH)(to) HCOONa + alcohol The structure of C is :
From the following sequence of reactions , [A] (C_(6)H_(12)) overset(HCl)(rarr) (B) (C_(6) H_(13)Cl) + (C) (C_(6)H_(13)Cl) react with AgNO_(3) to give white ppt. [B] overset("Alc." KOH)(to) (D) (An isomer of A ) gives positive test with Br_(2)//C Cl_(4) [D] overset("Ozonelysis")(to) (E) gives positive iodoform test and negative Fehling's test . [A] overset("Ozonolysis")(to) (F) + (G) , both F and G give positive Tollen's test . [F] + [G] underset(Delta)overset("Conc." NaOH)(to) HCOONa + alcohol The reaction involve in F and G with the NaOH is : The reaction involve in the F and G with NaOH is :
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