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DeltaG = DeltaH - TDeltaS and DeltaG + T...

`DeltaG = DeltaH - TDeltaS` and `DeltaG + T[(d(DeltaG))/(dT)]_(p)` then `((dE_(cell)/(dT))` is:

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If DeltaG=DeltaH-TDeltaS and DeltaG = DeltaH+T[(d(DeltaG))/(dT)] , then variation EMF of a cell E, with temperature T, is given by

Establish DeltaG = DeltaH- TDeltaS .

The cell potential (E_("cell")) of a reaction is related as DeltaG = -nFE_("cell") , where DeltaG represents max. useful electrical work . n=no. of moles of electrons exchanged during the reactino of reversible cell reaction d(DeltaG) = (DeltaV)dP-(DeltaS).dT at constant pressure d(DeltaG) = - (DeltaS).dT :' At constant pressure DeltaG = DeltaG = DeltaH-TDeltaS .......(1) :. DeltaG = DeltaH + T((d(DeltaG))/(dT))_P ......... (B) ((dE_("cell"))/(dT))_(P) is known as temperature coefficient of the e.m.f of the cell When DeltaS increases, temperature coefficient of the emf of cell