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Levelling Effect...

Levelling Effect

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Arrange the different sub-energy levels in the decreasing order of screening effect.

Screening effect is the effect produced by intervening electrons between nucleus and valence electrons . They shield the nucleus from valence electron and effective nuclear charge decreases if there is less shielding effect the effective nuclear charge decreases Valence electrons are attracted by nucleus and repelled by other electrons. Net effective force on electrons under consideration = Z-sigma = (Nuclear charge -screening effect ) slaters formula for screening constant. If one electron is present in outermost orbit there will be no screening in that orbital. Each electrons contributes 0.35 (total electrons minus 1) present in outermost shell. In penultimate energy level electrons contribute 0.85. A contribution of 1 is from remaining electrons (present in last but one energy level) The effective nuclear charge for 4s electrons of Zn will be

Screening effect is the effect produced by intervening electron between nucleus and valence electrons. They shield the nucleus from valence electron and effective nuclear charge decreases if there is less shielding effect, the effective nuclear charge decreases. Balance electrons are attracted by nucleus and repelled by other electrons. Net attractive force on electron under consideration =Z- sigma = (Nuclear charge screening effect) which is Slater's formula for screening constant. If one electron is present in outermost orbit, there will be no screening in that orbital. Each electron contributes 0.35 (total electrons minus 1) present in outermost shell. In penultimate energy level, electrons contribute 0.85. A contribution of 1.0 is from remaining electrons (present in last but one energy level). The effective nuclear charge for 4s electrons of Zn will be

Assertion: (A) Generally, ionsiation enthalpy increases from left to right in a period. Reason ( R) When successive electrons are added to the orbitals in the same principle quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electrons to the nucleus.

Assertion: (A) Generally, ionsiation enthalpy increases from left to right in a period. Reason ( R) When successive electrons are added to the orbitals in the same principle quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electrons to the nucleus.

Statement-1: Generally, ionisation enthalpy increases from left to right in a period. Statement-2: When successive electrons are added to the orbitals in the same principal quantum level, the shielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus.

Assertion: Generally, ionisation enthalpy than beryllium. Reason: When successive electrons are added to the orbitals in the same principle quantum level, the shiielding effect of inner core of electrons does not increase very much to compensate for the increased attraction of the electron to the nucleus.