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According to the Rydberg formula, the wa...

According to the Rydberg formula, the wavelengths of the first two spectral line in the Lyman series of the hydrogen spectrum, are

A

`912 Å` & `3684 Å`

B

`684 Å` & `811 Å`

C

`1218 Å` & `1028 Å`

D

`915.4 Å` & `974.3 Å`

Text Solution

Verified by Experts

The Rydberg formula is
`hc//lambda_(g)=(me^(4))/(8epsilon_(0)^(2)h^(2))((1)/(n_(f)^(2)-n_(i)^(2)))`
The wavelength of the first four lines in the Lyman series correspond to transitions from `n_(i)=2,3,4,5` to `n_(f)=1`. We know that
`(me^(4))/(8epsilon_(0)^(2)h^(2))=13.6eV=21.76xx10^(-19)J`
Therefore,
`lambda_(i1)=(hc)/(21.76xx10^(-19)((1)/(1)-(1)/(n_(i)^(2))))m=(0.9134n_(i)^(2))/((n_(i)^(2)-1))xx10^(-7)m`
`=913.4n_(i)^(2)//(n_(i)^(2)-1)A`
Substituting `n_(i)=2,3` we get `lambda_(21) 1218 Å`, `lambda_(31)1028Å`
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