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Select the correct statement (i). Delo...

Select the correct statement
(i). Delocalisation of `sigma`-electron is hyperconjugation.
(ii). Delocalisation of `pi`-electron is resonance.
(iii). Partial displacement of `sigma`-electron is inductive effect.

A

(i) & (iii)

B

(ii) & (iii)

C

(i) & (ii)

D

(i),(ii),(iii)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to evaluate the three statements provided regarding the concepts of hyperconjugation, resonance, and inductive effect in organic chemistry. ### Step-by-Step Solution: 1. **Evaluate Statement (i)**: - The statement claims that "Delocalisation of sigma-electron is hyperconjugation." - **Analysis**: Hyperconjugation involves the delocalization of sigma electrons from C-H or C-C bonds to an adjacent empty or partially filled p-orbital or π-bond. This statement is **correct**. 2. **Evaluate Statement (ii)**: - The statement claims that "Delocalisation of pi-electron is resonance." - **Analysis**: Resonance refers to the delocalization of pi electrons across adjacent atoms through the overlap of p-orbitals, leading to the stabilization of the molecule. This statement is also **correct**. 3. **Evaluate Statement (iii)**: - The statement claims that "Partial displacement of sigma-electron is inductive effect." - **Analysis**: The inductive effect refers to the permanent polarization of sigma bonds due to electronegativity differences between atoms. It involves the shifting of sigma electrons towards more electronegative atoms, which is indeed a correct description of the inductive effect. This statement is also **correct**. ### Conclusion: All three statements are correct. Therefore, the correct answer is that **all statements (i), (ii), and (iii) are correct**.
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BANSAL-GENERAL ORGANIC CHEMISTRY-Exercise 1
  1. Arrange acididy of given compounds in decreasing order (I). CH(3)-N-...

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  2. Hyperconjugation is best decribe as:

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  3. Select the correct statement (i). Delocalisation of sigma-electron i...

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  4. Which of the following compound is non aromatic:

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  5. underset((I))(CH(2)=CH-CH=CH-CH(3)) is more stable than underset((II))...

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  6. Which of the following is not a valid resonating of the other three?

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  7. In which of the following molecules pi-electron density in ring is max...

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  8. In which of the following molecules pi-electron density in ring is min...

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  9. Which of the following has longest C-O bond

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  10. Select the least stble resonating structure in each of the following s...

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  11. Select the most stable intermediate

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  12. Write correct order regarding stability of intermediates (I). CH(2)=...

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  13. Rate of abstraction of iodine by Ag^(o+) is

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  14. Which of the following alkene is most stable alkene.

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  15. Which of the following is lowest pKa value?

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  16. Which of the following will give effervesce of CO(2) with NaHCO(3)

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  17. Select the one which does not results in the formation of aromatic spe...

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  18. Correct order of stability of these carbocatios is:

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  19. Correct order of stability-

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  20. Which of the following is a+I group

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