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The standard electrode potential for Dan...

The standard electrode potential for Daniel cell is `1.1V`. Calculate the standard Gibbs energy of the reaction (In KJ/mol)
`Zn_((s))+Cu_((aq))^(2+)rarrZn_((aq))^(2+)+Cu_((s))`

A

`106.15`

B

`212.3`

C

`193`

D

`403`

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The correct Answer is:
To calculate the standard Gibbs energy (ΔG°) of the reaction for the Daniel cell, we can use the relationship between Gibbs free energy and standard electrode potential: \[ \Delta G° = -nFE° \] Where: - \( n \) = number of moles of electrons transferred in the reaction - \( F \) = Faraday's constant (approximately \( 96500 \, C/mol \)) - \( E° \) = standard electrode potential (in volts) ### Step-by-Step Solution: 1. **Identify the number of electrons transferred (n)**: In the given reaction: \[ \text{Zn}_{(s)} + \text{Cu}^{2+}_{(aq)} \rightarrow \text{Zn}^{2+}_{(aq)} + \text{Cu}_{(s)} \] Each zinc atom loses 2 electrons to become \( \text{Zn}^{2+} \) and each copper ion gains 2 electrons to become copper metal. Therefore, the number of electrons transferred \( n \) is 2. **Hint**: Look for how many electrons are involved in the oxidation and reduction processes in the half-reactions. 2. **Use the given standard electrode potential (E°)**: The standard electrode potential for the Daniel cell is given as \( E° = 1.1 \, V \). **Hint**: Remember that the standard electrode potential is a measure of the driving force behind the redox reaction. 3. **Use Faraday's constant (F)**: The value of Faraday's constant is \( F = 96500 \, C/mol \). **Hint**: Faraday's constant represents the charge of one mole of electrons. 4. **Substitute the values into the Gibbs energy equation**: Now we can substitute the values into the equation: \[ \Delta G° = -nFE° \] \[ \Delta G° = -2 \times 96500 \, C/mol \times 1.1 \, V \] 5. **Calculate ΔG°**: \[ \Delta G° = -2 \times 96500 \times 1.1 = -212130 \, J/mol \] 6. **Convert to kilojoules**: To convert joules to kilojoules, divide by 1000: \[ \Delta G° = -212130 \, J/mol \div 1000 = -212.13 \, kJ/mol \] ### Final Answer: \[ \Delta G° \approx -212.3 \, kJ/mol \] ### Summary: The standard Gibbs energy of the reaction for the Daniel cell is approximately \(-212.3 \, kJ/mol\).

To calculate the standard Gibbs energy (ΔG°) of the reaction for the Daniel cell, we can use the relationship between Gibbs free energy and standard electrode potential: \[ \Delta G° = -nFE° \] Where: - \( n \) = number of moles of electrons transferred in the reaction ...
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