Home
Class 12
CHEMISTRY
When 1pentyne (A) is treated with 4N alc...

When `1`pentyne `(A)` is treated with `4N` alcoholic `KOH` at `175^(@)C`, it is slowly converted into an equilibrium mixture of `1.3%` of `1`pentyne `(A), 95.2% 2`-pentyne `(B)` and `3.5%` of `1,2`-pentandiene `(C )`. The equilibrium was maintained at `175^(@)C`. calculate `DeltaG^(Theta)` for the following equilibria:
`B hArr A, DeltaG^(Theta)underset(1) = ?`
`B hArr C, DeltaG^(Theta)underset(2) =?`
From the calculated value of `DeltaG^(Theta)underset(1)`and `DeltaG^(Theta)underset(2)`, indicate the order of stability of `A,B` and `C`.

Text Solution

Verified by Experts

The correct Answer is:
(12.3 kJ)
Promotional Banner

Topper's Solved these Questions

  • SURFACE CHEMISTRY

    IIT-JEE PREVIOUS YEAR (CHEMISTRY)|Exercise JEE Main And Advanced|17 Videos

Similar Questions

Explore conceptually related problems

Determine the values of equilibrium constant (K_C) and DeltaG^o for the following reaction :

What is the sign of DeltaG^(Theta) and the values of K for an electrochemical cell for which E^(Theta)underset(cell) = 0.80volt ?

Which is not correct relationship between DeltaG^(Theta) and equilibrium constant K_(P) .

The value of (cos3 theta)/(2cos2 theta-1) is equal to cos theta(b)sin theta (c) tan theta(d) none of these

IIT-JEE PREVIOUS YEAR (CHEMISTRY)-THERMODYNAMICS AND THERMOCHEMISTRY-JEE Main And Advanced
  1. 100mL of a liquid is contained in an insulated container at a pressure...

    Text Solution

    |

  2. Two moles of a perfect gas undergo the following process: (a) A revers...

    Text Solution

    |

  3. When 1pentyne (A) is treated with 4N alcoholic KOH at 175^(@)C, it is ...

    Text Solution

    |

  4. Show that the reaction CO(g) +(1//2)O(2)(g) rarr CO(2)(g) at 300K ...

    Text Solution

    |

  5. A sample of argon gas at 1atm pressure and 27^(@)C expands reversibly ...

    Text Solution

    |

  6. A gas mixture of 3.67L of ethylene and methane on complete combustion ...

    Text Solution

    |

  7. An athelete is given 100g of glucose (C(6)H(12)O(6)) of energy equival...

    Text Solution

    |

  8. The following statement is true only under some specific conditions. W...

    Text Solution

    |

  9. With the help of thermochemical equations given below, determine Delta...

    Text Solution

    |

  10. The enthalpies of combustion of carbon and carbon monoxide are -393.5 ...

    Text Solution

    |

  11. For the complete combustion of ethanol, C(2)H(5)OH(l)+3O(2)(g)rarr2CO(...

    Text Solution

    |

  12. The standard enthalpies fo formation of CO(2) (g), H(2) O (1), and glu...

    Text Solution

    |

  13. Using the data provided, calculate the multiple bond energy (kJ mol^(-...

    Text Solution

    |

  14. The species which by definition has zero standard molar enthalpy of fo...

    Text Solution

    |

  15. The bond energy (in kcal mol^(-1)) of a C -c single bond is approximat...

    Text Solution

    |

  16. Delta(vap)H = 30 kJ mol^(-1) and Delta(vap)S = 75 Jmol^(-1)K^(-1). Fin...

    Text Solution

    |

  17. Which of the reaction defines Delta(f)H^(@) ?

    Text Solution

    |

  18. Delta H(1)^(@) for CO(2)(g), CO(g) and H(2)O(g) are -393.5,-110.5 and ...

    Text Solution

    |

  19. The following is (are) endothermic reaction (s)

    Text Solution

    |

  20. In a constant volume calorimeter, 3.5 g of a gas with molecular weight...

    Text Solution

    |