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With the help of thermochemical equations given below, determine `Delta_(r )H^(Θ)` at `298 K` for the following reaction:
`C("graphite")+2H_(2)(g) rarr CH_(4)(g),Delta_(r )H^(Θ) = ?`
`C("graphite")+O_(2)(g) rarr CO_(2)(g),
Delta_(r )H^(Θ) = -393.5 kJ mol^(-1)` ...(1)
`H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l)`,
`Delta_(r )H^(Θ) = -285.8 kJ mol^(-1)` ...(2)
`CO_2(2)(g)+2H_(2)O(l) rarr CH_(4)(g)+2O_(2)(g)`,
`Delta_(r )H^(Θ) = +890.3 kJ mol^(-1)` ...(3)

A

`+ 78.8kJ mol^(-1)`

B

`+144.0kJ mol^(-1)`

C

`- 74.8kJ mol^(-1)`

D

`-144.0kJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
c
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Calculate the heat of combustion (in KJ) of methane from the following data (i) C ("graphite")+2H_(2)(g) rarr CH_(4) (g), DeltaH=-74.8 kJ (ii) C ("graphite")+O_(2) (g) rarr CO_(2) (g), DeltaH=-393.5 kJ (iii) H_(2(g))+1//2O_(2(g)) rarr H_(2)O_((l)), DeltaH=-286.2 kJ .

Calculate enthalpy of formation of methane (CH_4) from the following data : (i) C(s) + O_(2)(g) to CO_(2) (g) , Delta_rH^(@) = -393.5 KJ mol^(-1) (ii) H_2(g) + 1/2 O_(2)(g) to H_(2)O(l) , Deta_r H^(@) = -285.5 kJ mol^(-1) (iii) CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O(l), Delta_(r)H^(@) = -890.3 kJ mol^(-1) .

Calculate in kJ for the following reaction : C(g) + O_(2)(g) rarr CO_(2)(g) Given that, H_(2)O(g) + C(g) + H_(2)(g) , Delta H = +131 kJ CO(g) + 1/2 O_(2)(g) rarr CO_(2)(g), " " Delta H = -242 kJ H_(2)(g) + 1/2 O_(2)(g) rarr H_(2)O(g), " "DeltaH = -242 kJ

Calculate the standard enthalpy of formation of CH_(3)OH(l) from the following data: CH_(3)OH(l)+3/2O_(2)(g) rarr CO_(2)(g)+2H_(2)O(l), …(i), Delta_(r)H_(1)^(Θ)=-726 kJ mol^(-1) C(g)+O_(2)(g) rarr CO_(2)(g), …(ii), Delta_(c )H_(2)^(Θ)=-393 kJ mol^(-1) H_(2)(g)+1/2O_(2)(g) rarr H_(2)O(l), ...(iii), Delta_(f)H_(3)^(Θ)=-286 kJ mol^(-1)

Calculate the enthalpy of formation of methane from the following data : C(s) + O_(2)(g) to CO_(2)(g) Delta_(r)H^(@) = -393.5 kJ 2H_(2)(g) + O_(2)(g) to 2H_(2)O(l) Delta_(r)H^(@) = -571.8 kJ CH_(4)(g) + 2O_(2)(g) to CO_(2)(g) + 2H_(2)O(l) Delta_(r)H^(@) = -890.3 kJ

Calculate the enthalpy of formation of ethyl alcohol from the following data : C_(2)H_(5)OH(l) + 3O_(2)(g) to 2CO_(2)(g) + 3H_(2)O(l), Delta_(r)H^(@) = -1368.0 kJ C(s) +O_(2)(g) to CO_(2)(g), Delta_(r)H^(@) = -393.5 kJ H_(2)(g) + 1/2O_(2)(g) to H_(2)O(l), Delta_(r)H^(@) = -286.0 kJ

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