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Bond distance C-F in (CF(4)) & Si-F in ...

Bond distance `C-F` in `(CF_(4))` & `Si-F` in `(SiF_(4))` are respective `1.33 Å` & `1.54 Å. C-SI` bond is `1.87 Å`. Calculate the colvalent radius of F atom ignoring the electronegativity differences.

A

`0.64 Å`

B

`(1.33 +1.54 +1.8)/(3) Å`

C

`0.5 Å`

D

`(1.54)/(2) Å`

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The correct Answer is:
To calculate the covalent radius of the fluorine atom (F) in the compounds CF₄ and SiF₄, we can use the bond length data provided and the formula for bond lengths in covalent compounds. ### Step-by-Step Solution: 1. **Identify the Given Data:** - Bond distance C-F in CF₄ = 1.33 Å - Bond distance Si-F in SiF₄ = 1.54 Å - Bond distance C-Si in SiF₄ = 1.87 Å 2. **Set Up the Equations:** - The bond length formula states that: \[ \text{Bond Length (AB)} = r_A + r_B - 0.09 \times \Delta EN \] - Since we are ignoring the electronegativity differences, we can simplify this to: \[ \text{Bond Length (AB)} = r_A + r_B \] 3. **Write the Equations for CF₄ and SiF₄:** - For CF₄: \[ r_C + r_F = 1.33 \quad \text{(Equation 1)} \] - For SiF₄: \[ r_Si + r_F = 1.54 \quad \text{(Equation 2)} \] 4. **Add the Two Equations:** - Adding Equation 1 and Equation 2: \[ (r_C + r_F) + (r_Si + r_F) = 1.33 + 1.54 \] \[ r_C + r_Si + 2r_F = 2.87 \quad \text{(Equation 3)} \] 5. **Use the C-Si Bond Length:** - From the bond length of C-Si: \[ r_C + r_Si = 1.87 \quad \text{(Equation 4)} \] 6. **Substitute Equation 4 into Equation 3:** - Substitute \( r_C + r_Si \) from Equation 4 into Equation 3: \[ 1.87 + 2r_F = 2.87 \] 7. **Solve for \( r_F \):** - Rearranging gives: \[ 2r_F = 2.87 - 1.87 \] \[ 2r_F = 1.00 \] \[ r_F = 0.5 \, \text{Å} \] ### Final Answer: The covalent radius of the fluorine atom (F) is **0.5 Å**.

To calculate the covalent radius of the fluorine atom (F) in the compounds CF₄ and SiF₄, we can use the bond length data provided and the formula for bond lengths in covalent compounds. ### Step-by-Step Solution: 1. **Identify the Given Data:** - Bond distance C-F in CF₄ = 1.33 Å - Bond distance Si-F in SiF₄ = 1.54 Å - Bond distance C-Si in SiF₄ = 1.87 Å ...
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