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At 300K , the standard enthalpies of for...

At `300K` , the standard enthalpies of formation of `C_(6)H_(5)COOH_((s),CO_(2(g))` and `H_(2)O_((l))` are `-408,-393` and `-286kJ mol^(-1)` respectively. Calculate the heat of combustion of benzoic acid at
`(i)` constant pressure,
`(ii)` constant volume. `(R=8.31J mol^(-1)K^(-1))`

A

`-2629 KJ`

B

`-2751 KJ`

C

`-2808 KJ`

D

`-3201 KJ`

Text Solution

Verified by Experts

The correct Answer is:
D

`C_(6)H_(5)COOH_((5))+(15)/(2)O_(2(g))to 7CO_(2(g))+3H_(2)O_((R ))`
`Delta H = [7xx(-393)+3xx(-286]-[(-408)+0]`
`=-3201 kJ`
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