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If electron of hydrogen atom is replaced...

If electron of hydrogen atom is replaced by another particle of same charge but of double mass then:

A

Radii of orbits will increase

B

Ionisation energy will increase

C

Velocity of new particle will be more

D

Energy gap between two levels will be doubled

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The correct Answer is:
To solve the question regarding the effects of replacing the electron in a hydrogen atom with a particle of the same charge but double the mass, we can analyze the situation step by step. ### Step-by-Step Solution: 1. **Understanding the Hydrogen Atom Structure**: - A hydrogen atom consists of one proton in the nucleus and one electron in orbit around it. The electron has a certain mass (denoted as \( m_e \)) and charge (\( -e \)). 2. **Replacing the Electron**: - We replace the electron with another particle that has the same charge (\( -e \)) but double the mass (\( 2m_e \)). 3. **Effect on the Radius of Orbit**: - The radius of the nth orbit in a hydrogen atom is given by the formula: \[ r_n \propto \frac{1}{m_e} \] - If we double the mass of the particle, the new radius \( r'_n \) becomes: \[ r'_n = \frac{r_n}{2} \] - Thus, the radius of the orbit decreases. 4. **Effect on Ionization Energy**: - Ionization energy is directly proportional to the mass of the electron: \[ \text{Ionization Energy} \propto m_e \] - If the mass is doubled, the new ionization energy \( E'_i \) becomes: \[ E'_i = 2E_i \] - Therefore, the ionization energy increases. 5. **Effect on Velocity of the Particle**: - The velocity of an electron in the nth orbit is given by: \[ v_n \propto \frac{1}{\sqrt{m_e}} \] - If the mass is doubled, the new velocity \( v' \) becomes: \[ v' = \frac{v_n}{\sqrt{2}} \] - Hence, the velocity of the particle decreases. 6. **Effect on Energy Gap Between Levels**: - The energy gap \( \Delta E \) between two energy levels is also proportional to the mass of the electron: \[ \Delta E \propto m_e \] - If the mass is doubled, the new energy gap \( \Delta E' \) becomes: \[ \Delta E' = 2\Delta E \] - Thus, the energy gap between levels doubles. ### Conclusion: Based on the analysis: - The radius of the orbit decreases (not increases). - The ionization energy increases. - The velocity of the particle decreases (not increases). - The energy gap between levels doubles. ### Final Answers: - **Correct Options**: B (Ionization energy will increase) and D (Energy gap between two levels will be doubled). - **Incorrect Options**: A (Radii of orbit will increase) and C (Velocity of new particle will be more).
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GRB PUBLICATION-ATOMIC STRUCTURE-Multiple Objective Type
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  14. Select the correct statement .

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  15. Choose the correct statements regarding 'Psi'.

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  18. Identify the correct statement (s) regarding 3p(z) orbital.

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