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The figure shows initial conditions of a...

The figure shows initial conditions of a uniform cylinder with frictionless pistons A and B held in shown position by mechanical stoppers.

If the mechanical stoppers holding piston A and B as shown in figure are removed and in the mean time `N_(2)O_(4) and O_(3)` gases separately undergo following reaction completely [Assume that temperature remains constant]
`N_(2)O_(4) rarr 2NO_(2)`
`2O_(3) rarr 3O_(2)`
Which statement is correct after all the pistons have attained their final positions (assume `sigma` to be same for all gases)?

A

`Z_(11)` will be highest for molecules of gas in compartment 1

B

Mean free path will be longest for molecules of gas in compartments2

C

`Z_(11)` will be same for all gases

D

Mean free path will be same for molecules of gas in all compartments

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The correct Answer is:
d
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The figure shows initial conditions of a uniform cylinder with frictionless pistons A and B held in shown position by mechanical stoppers. If the mechanical stoppers holding piston A and B as shown in figure are removed and in the mean time N_(2)O_(4) and O_(3) gases separately undergo following reaction completely [Assume that temperature remains constant] N_(2)O_(4) rarr 2NO_(2) 2O_(3) rarr 3O_(2) Which statement is incorrect after attaining final equilibrium state?

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If the equilibrium constant for the reaction, N_(2)O_(4)hArr2NO_(2) is K=[NO_(2)]^(2)//[N_(2)O_(4)] , then which of the graphs are correct at constant temperature?

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