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A,B and C are three elements forming a c...

A,B and C are three elements forming a compound in which their oxidation state are +2,+5, and -2 respectively. Which could not be the formula of compound?

A

`A_(2)(BC)`

B

`A_(2)(BC_(4))_(3)`

C

`A_(3)(BC_(4))_(2)`

D

`ABC_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which formula could not be the compound formed by elements A, B, and C with oxidation states of +2, +5, and -2 respectively, we need to ensure that the overall charge of the compound is neutral (i.e., the sum of the oxidation states equals zero). Let's analyze the possible combinations step by step. ### Step 1: Understanding Oxidation States - Element A has an oxidation state of +2. - Element B has an oxidation state of +5. - Element C has an oxidation state of -2. ### Step 2: Setting Up the General Formula Let’s denote: - The number of A atoms as \( x \) - The number of B atoms as \( y \) - The number of C atoms as \( z \) The total charge contributed by each element can be expressed as: - Charge from A: \( 2x \) - Charge from B: \( 5y \) - Charge from C: \( -2z \) ### Step 3: Writing the Charge Balance Equation For the compound to be neutral, the sum of the charges must equal zero: \[ 2x + 5y - 2z = 0 \] ### Step 4: Analyzing Possible Formulas Let’s consider various combinations of \( x \), \( y \), and \( z \) to find which combinations do not satisfy the charge balance equation. 1. **Formula 1: \( A_2B_5C_2 \)** - Charge: \( 2(2) + 5(5) - 2(2) = 4 + 25 - 4 = 25 \) (not neutral) 2. **Formula 2: \( AB_3C_4 \)** - Charge: \( 1(2) + 3(5) - 4(2) = 2 + 15 - 8 = 9 \) (not neutral) 3. **Formula 3: \( A_3B_2C_8 \)** - Charge: \( 3(2) + 2(5) - 8(2) = 6 + 10 - 16 = 0 \) (neutral) 4. **Formula 4: \( A_2B_5C \)** - Charge: \( 2(2) + 5(5) - 1(2) = 4 + 25 - 2 = 27 \) (not neutral) ### Step 5: Conclusion From the analysis, the formulas that could not be the compound are: - Formula 1: \( A_2B_5C_2 \) - Formula 2: \( AB_3C_4 \) - Formula 4: \( A_2B_5C \) Thus, the answer to the question is that the formulas \( A_2B_5C_2 \), \( AB_3C_4 \), and \( A_2B_5C \) cannot be valid formulas for the compound.
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