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Maximum mole of Na(4)[Cu(6)(S(2)O(3))(5)...

Maximum mole of `Na_(4)[Cu_(6)(S_(2)O_(3))_(5)]` which can be produced by 6 moles of `CuSO_(4)` and 10 moles of `Na_(2)S_(2)O_(3)` using following series of reaction-
`CuSO_(4)+Na_(2)S_(2)O_(3) to CuS_(2)O_(3)+Na_(2)SO_(4)`
`2CuS_(2)O_(3)+Na_(2)S_(2)O_(3) to Cu_(2)S_(2)O_(3)+Na_(2)S_(4)O_(6)`
`3Cu_(2)S_(2)O_(3)+2Na_(2)S_(2)O_(3) to Na_(4)[Cu_(6)(S_(2)O_(3))_(5)]`
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632 g of sodium thiosulphate (a_(2)S_(2)O_(3)) reacts with copper sulphate to form cuproc thiosulphate which is reduced by sodium thiosulphate to give cuprous compound which is dissolved in excess of sodium thiosulphate to form a complex compound sodium cuprothisosulphate (Na_(4)[Cu_(6)(S_(2)O_(3))_(5)]) , (MW=1033) CuSO_(4) + Na_(2)S_(2)O_(3) rarr CuS_(2)O_(3) + Na_(2)SO_(4)" " [very fast] 2CuSO_(4)+Na_(2)S_(2)O_(3)+Na_(2)S_(2)O_(3) rarr Cu_(2)S_(2)O_(3) + Na_(2)S_(4)O_(6) 3Cu_(2)S_(2)O_(3) + 2Na_(2)S_(2)O_(3) rarr Na_(4)[Cu_(6)(S_(2)O_(3))_(5)] " " (Sodium cuprothisoulphate ) In this process , 0.2 mole of sodium cuprothiosulphate is formed .(O=16 , Na=23 , S=32) Moles of sodium thiosulophate reacted and unreacted after the reaction are respectively,

S_(8)+NaOH to Na_(2)S+Na_(2)S_(2)O_(3)

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