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When 50% solution of H(2)SO(4) is electr...

When 50% solution of `H_(2)SO_(4)` is electrolysed by passing a current of high density at low temperature the main products of electrolysis are:

A

oxygen and hydrogen

B

`H_(2)` and peroxy disulphuric acid

C

`H_(2)` and `SO_(2)`

D

`O_(2)` and peroxy disulphuric acid

Text Solution

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The correct Answer is:
B

`2H_(2)SO_(4)hArr2H^(+)+2HSO_(4)^(-)`
Cathode `2H^(+)rarr2e^(-)+H_(2)`
Anode `2HSO_(4)^(-)rarrH_(2)S_(2)O_(8)` (peroxy disulphuric acid)+`2e^(-)`
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