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Statement I: 5,5-dimethyl-1,3-cyclohexan...

Statement I: 5,5-dimethyl-1,3-cyclohexanedione exists predominantely in its enol form, but 2,2-dimethyl-1,3-cyclohexanedione does not.
Statement II: 2,2-dimethyl-1,3-cylcohexane dione has less `alpha-`hydrogen atoms than 5,5-dimethyl -1,3-cyclohexanedioene.

A

If both statement-I and statement II are true & the statement II is a correct explanation of the statement I

B

If both statemetn -I and Statement II are True and Statement II is not a correct explanation of the Statement I

C

If Statement -I is True but the Statement -II is false

D

If Statement -I is false but the Statement -II is True.

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The correct Answer is:
B

[The enol from of 5,5-dimethyl-1,3-cyclohexanedione is stable due to chelation, but same is not true in 2,2-dimethyl 1,3-cyclohexanedione due to absence of `alpha`-hydrogen because it is not having more acidic hydrogen].
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BANSAL-ISOMERISM-Exercise -2
  1. Statement I: Cyclohex -2,5-diene-1-one does not show tautameris. Sta...

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  2. Statement I: Me-C-=N and Me -Nvec(=)C are not functional isomers. St...

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  3. Statement I: 5,5-dimethyl-1,3-cyclohexanedione exists predominantely i...

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  4. Statement I: Resonating structures of can show geometrical isomerism ...

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  5. Which compound show tautomerism :

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  6. Which of the following compounds have higher enolic content than Keto ...

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  7. Which compound show tautomerism :

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  8. Enolic form of acetyl acetone is stablised due to :

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  9. Which of the following is/are correct matchings ?

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  10. In which of the following has minimum torsional strain and minimum van...

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  11. Tautomer of which of the follwing can show geometrical isomerism

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  12. Which will show geometrical isomerism ?

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  13. Which of the following constitutional isomerism is exhibited by alkane...

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  14. The IUPAC name of the compounds :

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  15. Which of the following compounds are optically active ?

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  16. Which of out the following are Non-resolvable.

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  17. Which of out of the following are resolvable.

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  18. Which conformation of n-Butane has both plane of summetry and centre o...

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  19. Which of the following pairs of compound is/are identical ?

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  20. Consider the following structure and pich by the right statement :

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