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Sodium carbonate can be manufactured by ...

Sodium carbonate can be manufactured by Solvay's process but potassium carbonate cannot be prepared because :

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Potassium carbonate can be obtained by Solvay's process.

Potassium carbonate can be obtained by Solvay's process.

Na_2CO_3 can be manufactured by Solvay's process but K_2CO_3 can not be prepared because

Potassium carbonate cannot be prepared by Solvay process. Why?

Potassium carbonate cannot be prepared by Solvay process. Why?