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Other than the X-ray difference , how co...

Other than the X-ray difference , how could be the following pairs of isomers be distinguished from one another by :
`[Cr(NH_(3))_(6)][Cr(NO_(2))_(6)] and [Cr(NH_(3))_(4)(NO_(2))_(2)][Cr(NH_(3))_(2)(NO_(2))_(4)]`

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