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Is the shape of a tetrahedral void tetra...

Is the shape of a tetrahedral void tetrahedral? If not, why is it so called?

Text Solution

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The shape of a tetrahedral void is not tetrahedral. This void is so named because in a close-packed structure of particles, it is formed due to tetrahedral disposition of four nearest neighbour particles.
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Knowledge Check

  • The number of packed particles in a cubic close-packed structure is x. If the number of tetrahedral and octahedral holes in this structure are y and z, then-

    A
    x = y = z
    B
    x = y = 2z
    C
    x = 2y = 2z
    D
    `x=y/2=z`
  • Which of the following is not tetrahedral ?

    A
    `BF_4^-`
    B
    `NH_4^+`
    C
    `CO_3^(2-)`
    D
    `SO_4^(2-)`
  • No. of tetrahedral voids per unit cell in NaCl crystal is-

    A
    4
    B
    8
    C
    twice the number of octahedral voids
    D
    four times the number of octahedral voids
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    The regular three dimensional arrangement of points in a crystal is known as crystal lattice and the smallest repeating pattern in the lattice is called unit cell. The unit cells are characterised by the edge lengths a, b, c and the angles between them alpha, beta and gamma respectively. Based on this, there are seven crystal systems. In a cubic unit cell: a=b=c and alpha = beta=gamma=90^(@) The number of points in simple, body centred and face centred cubic cells are 1,2 and 4 respectively In both the hcp and ccp of spheres, the number of tetrahedral voids per sphere is two while the octahedral voids is one. A double triangular void surrounded by three spheres above and three spheres below is called

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