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What is the significance of the terms-'I...

What is the significance of the terms-'Isolated gaseous atom' and 'ground tate' while defining the ionisation enthalpy ad electron-gain enthalpy?

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Ionisation energy of an element is defined as the minimum amount of energy required to remove the most loosely bound electron from the valence shell of an isolated gaseous atom existing in its ground state so as to form a cation in the gaseous state.
electron gain enthalpy is defined as the enthalpy change involved when an electron is added to an isolated gaseous atom in its lowest energy state (ground state) to form a gaseous ion carrying unit negative charge.
the force with which an electron gets attracted by the nucleus of an atom is influenced by the presence of other atoms in the molecule or in the neighbourhood. thus, to determine the iohnisation enthalpy. the interatomic forces should be minimum. interatomic forces are minimum to case of gaseous state as the atoms are far apart from each other. consequently, the value of ionisation enthalpy is less affected by the surroundings. similarly, for electron affinity, the interatomic forces of attraction should be minimum for the corresponding atom.for this reason, the term "isolated gaseous atom' is used while defining ionisation enthalpy and electron-gain enthalpy. ground state means the state at which the atom exists. in the most stable state. if the atom is in the excited state, then amount of heat applied to remove an electron or the amount of heat liberated due to addition of an electron is low. so, for the pupose of comparison the term 'ground state' is used while defining ionisation enthalpy and electron-gain enthalpy.
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CHHAYA PUBLICATION-CLASSIFICATION OF ELEMENTS & PERIODICITY IN PROPERTIES-SOLVED NCERT EXERCISE
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  2. Explain why cations are smaller and anions larger in radii than their ...

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  3. What is the significance of the terms-'Isolated gaseous atom' and 'gro...

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  4. Enegy of an electron in the ground state of the H. atom is -2.18xx10^(...

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  5. Among the second period elements the actual ionisation enthalpies are ...

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  6. How would you explain the fact that the first ionisation enthalpy of s...

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  7. What are the vairous factors due to which the ionisation enthalpy of t...

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  8. First ionisation enthalpy values (in kJ mol^(-1)) of group-13 elements...

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  9. Which of the given pairs would have a more negative electron-gain enth...

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  10. Electron gain enthalpy of Cl is more negative than F though electroneg...

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  11. What is the basic difference between the terms electron-gain enthalpy ...

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  12. How would you react to the statement that the electronegativity of N o...

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  13. Describe the theory associated with the radius of an atom as it (1) ...

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  14. Would you expect the first ionisation enthalpies for two isotopes of t...

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  15. What are the major differences between metals and non-metals?

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  16. Use the periodic table in answer the given questions. (1) Identify a...

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  17. The order of reacivity of grou-1 elements is Li lt Na lt K lt Rb lt Cs...

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  18. Write the general outer electronic configuration of s-,p-,d- and f-blo...

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  19. Assign the position of the element having outer electronic configurati...

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  20. The first (Delta(i)H(1)) and second (Delta(i)H(2)) ionisation enthalpy...

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