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The formation of the oxide ion O^(2-)(g)...

The formation of the oxide ion `O^(2-)(g)`, form oxygen atom requires first an exothermic and then an endothermic step as shown below,
`O(g)+e^(-) to O^(-)(g),DeltaH_(f)^(0)=-141kJ*mol^(-1)`
`O^(-)(g)+e^(-) to O^(2-)(g),DeltaH_(f)^(0)=+780kJ*mol^(-1)` ltbr. Thus, process of formations of `O^(2-)` in gas phase is unfavourable even through `O^(2-)` is isoelectronic with neon. it is due to the fact that-

A

electron repulsion outweighs the stability gained by achieving noble gas configuration

B

`O^(-)` ion has comparatively smaller size than O-atom

C

oxygen is more electronegative

D

addition of electron in O result in larger size of the ion

Text Solution

Verified by Experts

The correct Answer is:
A

Electron repulsion predominates over the stability gained by achieving noble gas configuration. Hence, formation of `O^(2-)` in gas phase is unfavourable.
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The formation of the oxide ion O^2-(g) from oxygen atom requires first an exothermic and then an endothermic step as shown below: O(g)+e^ rarr O^-(g),delta _t H=-1.41kJ mol^-1 , O^-(g)+e^- rarr O^2-(g),delta_t H=+1780 kjmol^-1 thus process of formation of O^2- in gas phase is unfavourable even though O^2- is isoelectronic with neon it is due to the fact that

Comment on the thermodynamic stability of NO(g). Given: (1)/(2)N_(2)(g)+(1)/(2)O_(2)(g)toNO(g),Delta_(r)H^(0)=90kJ*mol^(-1),NO(g)+(1)/(2)O_(2)(g)toNO_(2)g,Delta_(r)H^(0)=-74kJ*mol^(-1) .

Given (at 25^(@)C and 1 atm pressure): C(s, diamond) +O_(2)(g)toCO_(2)(g),DeltaH^(0)=-393.5kJ*mol^(-1) C(s, graphite) +O_(2)(g)toCO_(2)(g),DeltaH^(0)=-391.6kJ*mol^(-1) Find the standard heat of transition from graphite to diamond.

Calculate the entropy change at 0^(@) C for the process- H_(2)O(s) to H_(2)O(l) . Given: At 0^(2)C" "C_(2)O(s)toH_(2)O(g),DeltaH=51885J*mol^(-1) and H_(2)O(l)toH_(2)O(g),DeltaH=45860J*mol^(-1) .

Calculate the bond energy of O-H bond in H_(2)O(g) at the standard state from the following data: (1) H_(2)(g) to 2H(g),DeltaH^(0)=436kJ*mol^(-1) (2) (1)/(2)O_(2)(g)toO(g),DeltaH^(0)=249k*mol^(-1) (3) H_(2)(g)+(1)/(2)O_(2)(g)toH_(2)O(g),DeltaH_(f)^(0)[H_(2)O(g)]=-241.8kJ*mol^(-1) .

Why are the standard reaction enthalpies of the following two reactions different? (1) C(graphite, s) +O_(2)(g)toCO_(2)(g),DeltaH^(0)=-393.5kJ (2) C(diamond, s) +O_(2)(g)toCO_(2)(g),DeltaH^(0)=-395.4kJ

Identify the exothermic and endothermic changes: (i) NO(g)+(1)/(2)O_(2)(g) to NO_(2)(g)+57.0kJ (ii) H_(2)O(s)+6.02kJ to H_(2)O(l) (iii) C(s)+H_(2)O(g)toCO(g)+H_(2)(g)-130kJ .

The bond dissociation energies of two O-H bond in water are: H_2O(g)rarr H(g)+OH(g), Delta H=497.8 KJ mol^(-1) OH(g)rarr H(g)+O(g), Delta H=428.5 KJ mol^(-1) bond energy of O-H bond is

Given (at 25^(@)C ): C(s, graphite) +(1)/(2)O_(2)(g)toCO(g),DeltaH^(0)=-110.5kJ*mol^(-1) (1)/(2)O_(2)(g)toO,DeltaH^(0)=+249.1kJ*mol^(-1) CO(g)toC(g)+O(g),DeltaH^(0)=1073.24kJ*mol^(-1) The standard enthalpy change for the process, C(s, graphite) toC(g) at 25^(@)C is-

CHHAYA PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE-ENTRANCE QUESTION BANK
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  2. Which has the maximum dipole moment-

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  3. The formation of the oxide ion O^(2-)(g), form oxygen atom requires fi...

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  4. In which of the following pairs, both the species are not isostructura...

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  5. Decreasing order of stability is-

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  6. Which one of the following compounds shows the presence of interamolec...

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  7. Which of the following pairs of ions are isoelectronic and isostructur...

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  8. Among the following which one is a wrong statement-

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  9. The hybridisations of atomic orbitals of nitrogen in NO(2)^(+),NO(3)^(...

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  10. Consider the molecules CH(4),NH(3) and H(2)O. Which of the given state...

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  11. Predict the correct order among the following-

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  12. The charge forming electron pair in the carbonion CH(3)C -=C exists in...

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  13. Match the compound given in column-I with the hybridisation and shape ...

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  14. Which of the following pairs of species have the same bond order-

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  15. The species, having bond angles of 120^(@) is-

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  16. Match the interhalonge compounds of column-I with the geometry in colu...

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  17. Consider the following species, CN^(+),CN^(-)NO and CN which one of th...

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  18. In the structure of ClF(3), the number of lone pairs of electrons on c...

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