In a certain polar solvent, `PCl_(5)` undergoes ioonisation as follows: `2PC l_(5) hArr PCl_(4)^(+)+PCl_(6)^(-)`, predict geometrical shapes of all the species involved.

In certain polar solvent, PCl_5 undergoes ionisation as follows: 2PCl_5 overset(rightarrow) PCl_4^+ + PCl_6^- . Predict geometrical shapes of all the species involved.

PCl_(5) (g) to PCl_(3) (g) + Cl_(2) (g) , in this chemical reaction -

Write the Kp expression for PCl_(5(g))hArr PCl_(3(g)) + Cl_(2(g))

In the soild state , PCl_(5) exists in the lonic form as [PCl_(4)]^(+) [PCl_(6)]^(-) . What are the shapes of these two ions ? Why ?

The equilibrium established during thermal dissociation of PCl_(5)(g) in a closed vessel is as follows: PCl_(5)(g)hArr PCl_(3)(g)+Cl_(2)(g) If the degree of dissociation of PCl_(5)(g) at equilibrium be 'x', then show that (1) 'x' is inversely proportional to the square root of the total pressure of reaction mixture at equilibrium and (2) 'x' increases with increase in volume of the system.

The shape of PCl_5 is

Dissociation of PCl_(5) decreases in presence of increase in Cl_(2) why ?

Account for the following: Solid PCl_(5) is ionic in nature.

Mention the shape of ions obatined when PCl_(5) reacts with BCl_(3) .

At 473K, equilibrium constant K_(c) for decomposition of PCl_(5) is 8.3x10^(-3) . If decomposition is depicted as, PCl_(5)(g)hArr PCl_(3)(g)+Cl_(2)(g), DeltaH_(r)^(0)=124.0kJ*mol^(-1) Write an expression for the reaction.