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a' and 'b' are van der waals constant fo...

a' and 'b' are van der waals constant for gases. Chlorine is more easily liquefied than ethane because-

A

a and b for `Cl_(2) lt a and b ` for `C_(2)H_(6)`

B

a for `Cl_(2) lt a ` for `C_(2)H_(6)` but b for `Cl_(2) gt b` for `C_(2)H_(6)`

C

a for `Cl_(2) gt a` for `C_(2)H_(6)` but b for `Cl_(2) ltb` for `C_(2)H_(6)`

D

a and b for `Cl_(2) gt a and b` for `C_(2)H_(6)`

Text Solution

Verified by Experts

The correct Answer is:
C

van der waals constant 'a' is a measure of intermolecular forces of attraction of a gas whereas 'b' is measure of the size of gas molecules. Hence, more is the value of 'a' more easily that gas will be liquiefied.
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CHHAYA PUBLICATION-STATES OF MATTER : GASES AND LIQUIDS-ENTRANCE QUESTION BANK
  1. Equal weights of ethane and hydrogen are mixed in an empty container a...

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  2. Compressibility factor for a real gas at high pressure-

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  3. a' and 'b' are van der waals constant for gases. Chlorine is more easi...

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  4. For gaseous state, if most probable speed is denoted by c, average spe...

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  5. if Z is a compressibility factor, van der waals equation at low pressu...

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  6. Ratio of masses of oxygen & nitrogen in a gaseous mixture is 1:4 ratio...

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  7. Intermolecular interaction that is dependent on the inverse cube of di...

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  8. Two closed bulbs of equal volume (V) containing an ideal gas initially...

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  9. A gas mixture was prepared by taking equal mole of CO and N(2). If tot...

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  10. Two gases A and B having the same volume diffuse through a porous part...

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  11. By what factor does average velocity of a gas molecule increase when t...

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  12. 50 mL of each gas A and B takes 150s and 200s respectively for effusin...

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  13. Set-I: O(2),CO(2),H(2) and He, Set-II: CH(4),O(2) and H(2). The gases...

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  14. A certain gas takes three times as long to effuse out as helium. Its m...

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  15. Maximum deviation from ideal gas is expected in case of-

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  16. Equal masses of H(2),O(2) and methane have been taken in a container o...

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  17. A gas such as carbon monoxide would be most likely to obey the ideal g...

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  18. Equal moles of hydrogen and oxygen gases are placed in a container wit...

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  19. The correction factor 'a' to be the ideal gas equation corresponds to-

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  20. Given van der waals constant 'a' of NH(3),H(2),O(2) and CO(2) are resp...

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