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Na(2)S+Na(2)[Fe(CN)(5)NO]rarrNa(4)[Fe(NH...

`Na_(2)S+Na_(2)[Fe(CN)_(5)NO]rarrNa_(4)[Fe(NH)_(5)nos],` oxidation number of Fe in reactant ( complex ) and product ( complex) are `:`

A

2, 1

B

2, 2

C

2, 3

D

3, 3

Text Solution

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The correct Answer is:
D
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S-1 : [Cr(NH_(3))_(6)]^(3+) is a inner orbital complex with S-2: The complex formed by joining the CN ligands to Fe^(3+) ion has theoretical value fo 'spin only' magnetic moment equal to 1.73 B.M. S-3: Na_(2)S+Na_(2)[Fe(CN)_(5)NO]rarrNa_(4)[Fe(CN)_(5)NOS], In reactan and product the oxidation states of iron are same

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