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The molar ionic conductances of octahedr...

The molar ionic conductances of octahedral complexes.
(I) `PtCl_(4).5NH_(3)" "` (II) `PtCl_(4).4NH_(3)`
(III) `PtCl_(4).3NH_(3)" "` (IV) `PtCl_(4).2NH_(3)`

A

`PltQltRltS`

B

`SltRltQltP`

C

`RltSltQltP`

D

`SltRltPltQ`

Text Solution

Verified by Experts

The correct Answer is:
B
`(P)[Pt(NH_(3))_(5)Cl]Cl_(3)rArr4ions`
`(Q)[Pt(NH_(3))_(4)Cl_(2)]Cl_(2)rArr3ions`
`(R)[Pt(NH_(3))_(3)Cl_(3)]ClrArr2ions`
`(S)[Pt(NH_(3))_(2)Cl_(4)]rArr0ions`
So,`PgtQgtRgtS`
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GRB PUBLICATION-COORDINATION COMPOUNDS-C. Werners Theory, EAN Rule
  1. Which of the following complex acts as reducing agent based on Sidgwic...

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  2. In the compound CoCl(3).5NH(3) :

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  3. The molar ionic conductances of octahedral complexes. (I) PtCl(4).5N...

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  4. Which one is the most likely structure of CrCl(3).6H(2)O if 2/3 of tot...

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  5. [Ni(CO)(x)] and [Fe(CO)(y)] what will be the value of x and y respecti...

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  6. Whch of the following will not follow sidgwick's EAN rule ?

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  7. The molecular formula Co(NH(3))(5)BrSo(4) have two isomeric form X and...

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  8. CoCl(3).4H(2)O is an anyhydrous binary solute hence its Werner's repre...

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  9. A complex of platinum, ammonia and chloride produces four ions per mol...

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  10. How many moels of AgCI would be obtained, when 100 mL of 0.1 M CO(NH(3...

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  11. One mole of complex compound Co(NH3)5Cl3 gives 3 moles of ions on diss...

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  12. Complexes [Co(SO(4))(NH(3))(5)]Br and [CoBr(NH(3))(5)]SO(4) can be dis...

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  13. Consider the following satements for Werner's theory : (P) Ligands a...

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  14. Which of the following is correct for both the following coordination ...

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  15. 50 ml of 0.2 M solution of a compound with empirical formula CoCl(3)....

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  16. Which of the following is non-conducting ?

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  17. Choose the complex entity which follow(s) EAN rule :

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  18. A solution containing 0.319 g of complex CrCl(3).6H(2)O was passed th...

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  19. Other than the X-ray difference , how could be the following pairs of ...

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  20. The EAN of metal atoms in [Fe(CO)(2)(NO^(+))(2)] and Co(2)(CO)(8) resp...

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