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Both Co^(3+) and Pt^(4+) have a coordina...

Both `Co^(3+) and Pt^(4+)` have a coordination number of six. Which of the following pair of complexes will show approximately the same electrical conductance for their `0.001` M aqueous solution ?

A

`CoCl_(3).4NH_(3)" and " PtCl_(4).4NH_(3)`

B

`CoCl_(3).3NH_(3)" and " PtCl_(4).5NH_(3)`

C

`CoCl_(3).6NH_(3)" and " PtCl_(4).5NH_(3)`

D

`CoCl_(3).6NH_(3)" and " PtCl_(4).3NH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
C

`CoCl_(3)*6NH_(3)rarr [Co(NH_(3))_(6)]Cl_(3)`
`PtCl_(4)*5NH_(3)rarr[Pt(NH_(3))_(5)Cl]Cl_(3)`
Both have 4 ions in their aq. Solution
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