Home
Class 12
CHEMISTRY
Low spin complex is formed by :...

Low spin complex is formed by :

A

`sp^(3)d^(2)` hybridization

B

`sp^(3)d` hybridization

C

`d^(2)sp^(3)` hybridization

D

`sp^(3)` hybridization

Text Solution

AI Generated Solution

The correct Answer is:
To determine which type of complex forms a low spin configuration, we need to analyze the characteristics of low spin complexes and the factors that influence their formation. ### Step-by-Step Solution: 1. **Understanding Low Spin Complexes**: - Low spin complexes are characterized by having fewer unpaired electrons. This occurs when the electrons are paired up in the lower energy orbitals due to the influence of strong field ligands. 2. **Identifying the Role of Ligands**: - Strong field ligands cause a significant splitting of the d-orbitals in transition metal complexes. This splitting leads to the pairing of electrons in the lower energy orbitals (t2g) before they occupy the higher energy orbitals (eg). 3. **Electron Configuration**: - For a d6 configuration, in the presence of a strong field ligand, all six electrons will pair up in the t2g orbitals, resulting in a low spin state. - Conversely, in the presence of weak field ligands, the electrons will occupy the higher energy orbitals before pairing, leading to a high spin state. 4. **Hybridization in Low Spin Complexes**: - In octahedral complexes, the hybridization can be d2sp3 or sp3d2. The d-orbitals involved in hybridization can be either the inner d-orbitals (3d) or the outer d-orbitals (4d). - For low spin complexes, the inner d-orbitals participate in hybridization, which allows for pairing of electrons. 5. **Conclusion**: - The formation of a low spin complex is associated with strong field ligands and hybridization involving inner d-orbitals. Therefore, the correct hybridization for a low spin complex is typically d2sp3. ### Final Answer: Low spin complexes are formed by strong field ligands that lead to d2sp3 hybridization.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise E. Stability, Colour and Magnetic Properties of Complexes|60 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise F.Isomerism in Coordination Compounds|124 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise C. Werners Theory, EAN Rule|63 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Subjective Type|63 Videos
  • D-BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Subjective Type|18 Videos

Similar Questions

Explore conceptually related problems

For which transition metal ions are low spin complexes possible:

Assertion : Inner orbital complexes are low spin complexes . Reason : In low spin complexes , inner d-orbital (3d) is used in hybridisation .

Assertion:- K_(3)[Fe)CN)_(6)] is an example of low spin complex. Reason:- This complex is paramagnetic in nature.

Low spin complex of d^6 -cation in an octahedral field will have the following energy:

Which of the following complex is a low spin complex ?

Which of the folliwing complex is inner orbital as well as low spin complex? .

GRB PUBLICATION-COORDINATION COMPOUNDS-D.VBT, CFT, Hybridisation
  1. The number of unpaired electrons in d^(6), low spin, octahedral comple...

    Text Solution

    |

  2. s-1: [MnCl(6)]^(3),[FeF(6)]^(3-) and [CoF(6)]^(-3) are paramagnetic ha...

    Text Solution

    |

  3. Low spin complex is formed by :

    Text Solution

    |

  4. Which of the following is a high spin complex ?

    Text Solution

    |

  5. Which has maximum paramagnetic character ?

    Text Solution

    |

  6. Which of the following is non-planar with respect to central atom ?

    Text Solution

    |

  7. [RhF(6)]^(3-) complex ion is :

    Text Solution

    |

  8. Which of the following molecule do not have the same number of unpaire...

    Text Solution

    |

  9. Among the following pair of complexes, in which case the triangle(0) v...

    Text Solution

    |

  10. {:(CuSO(4)+NH(4)OH to "Deep blue soluble"),(" excess...

    Text Solution

    |

  11. Which of the following is incorrect option ? {:(CuI(2)+KI to K(3)[Cu...

    Text Solution

    |

  12. The number of unpaired electrons present in complex ion [FeF(6)]^(3-) ...

    Text Solution

    |

  13. For cis platin which option is incorrect ?

    Text Solution

    |

  14. The crystl field splitting energy for octahedral complex (Delta(0)) an...

    Text Solution

    |

  15. Which of the following complexes has a geometry different from others ...

    Text Solution

    |

  16. FeSO(4)+KCN(excess) to "complex"" "X Which of the following option i...

    Text Solution

    |

  17. Consider the following complex ions. [CrCl(6)]^(3-)" "[Cr(H(2)O)...

    Text Solution

    |

  18. Which of the following complexes have a maximum number of unpaired ele...

    Text Solution

    |

  19. Which of the following complex is a low spin complex ?

    Text Solution

    |

  20. The tetrahedral [CoI(4)]^(2-) and square planar [PdBr(4)]^(2-) complex...

    Text Solution

    |