Home
Class 12
CHEMISTRY
Among the following pair of complexes, i...

Among the following pair of complexes, in which case the `triangle_(0)` value is higher for the first one?

A

`[Co(NH_(3))_(6)]^(3+)" and "[Co(CN)_(6)]^(3-)`

B

`[CoF_(6)]^(3-)" and "[Co(NH_(3))_(6)]^(3+)`

C

`[Co(H_(2)O)_(6)]^(2+)" and "[Co(H_(2)O)_(6)]^(3+)`

D

`[Rh(H_(2)O)_(6)]^(3+)" and "[Co(H_(2)O)_(6)]^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
D

Down the group, C.F. splitting increases `40-50%`.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise E. Stability, Colour and Magnetic Properties of Complexes|60 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise F.Isomerism in Coordination Compounds|124 Videos
  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise C. Werners Theory, EAN Rule|63 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Subjective Type|63 Videos
  • D-BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Subjective Type|18 Videos

Similar Questions

Explore conceptually related problems

Among the following pairs of complexes, in which case the Delta_(0) value is higher for the first one?

Among the following pair of complexes in which case the central atoms are having some hybridisation and have same values of E.A.N. also.

Among the following, the pair of paramagnetic complexes is

Which among the following pairs is wrong ?

Which among the following complexes is diamagnetic?

Among the following pair of reaction in which pair the second reaction is more reactive then first in S_(N^(2)) reaction ?

Among the following pair of reactions in which pair second reaction is more reactive than first for S_(N^(1)) reaction?

GRB PUBLICATION-COORDINATION COMPOUNDS-D.VBT, CFT, Hybridisation
  1. [RhF(6)]^(3-) complex ion is :

    Text Solution

    |

  2. Which of the following molecule do not have the same number of unpaire...

    Text Solution

    |

  3. Among the following pair of complexes, in which case the triangle(0) v...

    Text Solution

    |

  4. {:(CuSO(4)+NH(4)OH to "Deep blue soluble"),(" excess...

    Text Solution

    |

  5. Which of the following is incorrect option ? {:(CuI(2)+KI to K(3)[Cu...

    Text Solution

    |

  6. The number of unpaired electrons present in complex ion [FeF(6)]^(3-) ...

    Text Solution

    |

  7. For cis platin which option is incorrect ?

    Text Solution

    |

  8. The crystl field splitting energy for octahedral complex (Delta(0)) an...

    Text Solution

    |

  9. Which of the following complexes has a geometry different from others ...

    Text Solution

    |

  10. FeSO(4)+KCN(excess) to "complex"" "X Which of the following option i...

    Text Solution

    |

  11. Consider the following complex ions. [CrCl(6)]^(3-)" "[Cr(H(2)O)...

    Text Solution

    |

  12. Which of the following complexes have a maximum number of unpaired ele...

    Text Solution

    |

  13. Which of the following complex is a low spin complex ?

    Text Solution

    |

  14. The tetrahedral [CoI(4)]^(2-) and square planar [PdBr(4)]^(2-) complex...

    Text Solution

    |

  15. Which of the following can act as reducing agent ?

    Text Solution

    |

  16. Complex of HgCo.4SCN has two isomers X and Y then, which of the follow...

    Text Solution

    |

  17. Which of the following complex will be paramagnetic ? (Assume all cent...

    Text Solution

    |

  18. The compound which does not show paramagnetism is

    Text Solution

    |

  19. Which of the following statement is correct for the complex K(4)[Fe(CN...

    Text Solution

    |

  20. In [(H(2)O)(4)Co-(O-O)-Co (H(2)O)(4)] CL(5) complex, Co has t(2g)^(6)e...

    Text Solution

    |